Tetrahedron letters

Palladium (II)-catalyzed hydroarylation of α, β-unsaturated aldehydes and ketones with triarylstibines in the presence of silver acetate

CS Cho, K Tanabe, S Uemura

Index: Cho, Chan Sik; Tanabe, Koichiro; Uemura, Sakae Tetrahedron Letters, 1994 , vol. 35, # 8 p. 1275 - 1278

Full Text: HTML

Citation Number: 35

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Triarylstibines react with α,β-unsaturated aldehydes and ketones in acetic acid at 25°C in the presence of silver acetate and a catalytic amount of palladium(II) acetate to afford the hydroarylation products by conjugate addition in good yields. ... Triarylstibines react with enals and ...

 Related Synthetic Route
Crotonaldehyde Structure

123-73-9

Crotonaldehyde

tris(4-methylphenyl)stibane Structure

5395-43-7

tris(4-methylph...

~0%

BI-P-TOLYL Structure

613-33-2

BI-P-TOLYL

I(2),4-Dimethylbenzenepropanal Structure

16251-78-8

I(2),4-Dimethyl...

tris(p-anisyl)antimony Structure

21502-70-5

tris(p-anisyl)a...

3-penten-2-one Structure

3102-33-8

3-penten-2-one

~0%

4,4'-Dimethoxybiphenyl Structure

2132-80-1

4,4'-Dimethoxyb...

4-(4-methoxyphenyl)-2-pentanone Structure

69657-28-9

4-(4-methoxyphe...

Triphenylstibine Structure

603-36-1

Triphenylstibine

Methyl cinnamate Structure

103-26-4

Methyl cinnamate

~81%

Biphenyl Structure

92-52-4

Biphenyl

Methyl 3,3-diphenyl-2-propenoate Structure

3461-34-5

Methyl 3,3-diph...

Detail
Triphenylstibine Structure

603-36-1

Triphenylstibine

acrylic acid methyl ester Structure

292638-85-8

acrylic acid me...

~33%

Biphenyl Structure

92-52-4

Biphenyl

Methyl 3,3-diphenyl-2-propenoate Structure

3461-34-5

Methyl 3,3-diph...

Detail
Crotonaldehyde Structure

123-73-9

Crotonaldehyde

Triphenylstibine Structure

603-36-1

Triphenylstibine

~51%

Biphenyl Structure

92-52-4

Biphenyl

hyacinth butanal Structure

16251-77-7

hyacinth butanal

cyclohexenone Structure

930-68-7

cyclohexenone

Triphenylstibine Structure

603-36-1

Triphenylstibine

~43%

Biphenyl Structure

92-52-4

Biphenyl

3-Phenylcyclohexanone Structure

20795-53-3

3-Phenylcyclohe...

Mesityl oxide Structure

141-79-7

Mesityl oxide

Triphenylstibine Structure

603-36-1

Triphenylstibine

~13%

Biphenyl Structure

92-52-4

Biphenyl

2-Pentanone,4-methyl-4-phenyl- Structure

7403-42-1

2-Pentanone,4-m...

Triphenylstibine Structure

603-36-1

Triphenylstibine

trans-4-phenylbut-3-en-2-one Structure

1896-62-4

trans-4-phenylb...

~42%

Biphenyl Structure

92-52-4

Biphenyl

2-Butanone,4,4-diphenyl- Structure

5409-60-9

2-Butanone,4,4-...

Triphenylstibine Structure

603-36-1

Triphenylstibine

3-penten-2-one Structure

3102-33-8

3-penten-2-one

~41%

Biphenyl Structure

92-52-4

Biphenyl

4-phenylpentan-2-one Structure

17913-10-9

4-phenylpentan-2-one

ANTIMONY TRI-A-NAPHTHYL Structure

27309-70-2

ANTIMONY TRI-A-...

Methyl vinyl ketone Structure

78-94-4

Methyl vinyl ketone

~51%

binaphthyl Structure

604-53-5

binaphthyl

4-(1-Naphthyl)-3-buten-2-one Structure

66920-75-0

4-(1-Naphthyl)-...

Detail

Home | MSDS/SDS Database Search | Journals | Product Classification | Biologically Active Compounds | Selling Leads | About Us | Disclaimer

Copyright © 2024 ChemSrc All Rights Reserved