Cyclizations of ene radicals. Imidoyl radicals as intermediates in the synthesis of heterocyclic compounds

MD Bachi, D Denenmark

Index: Bachi, Mario D.; Denenmark, Daniella Journal of the American Chemical Society, 1989 ,  vol. 111,  # 5  p. 1886 - 1888

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Citation Number: 53

Abstract

The construction of cyclic systems through the intramolecular addition of carbon centered free radicals to carbon-arbon multiple bonds is well documented.'A convenient method for the sitespecific generation of carbon-centered free radicals involves the chemospecific homolysis of a C-halogen, CS, or C-Se bond by trialkyltin radicals generated from the corresponding tin hydrides2 The tin hydride induced free radical cyclizations are not ...