Experimental and theoretical study of Hoveyda–Grubbs catalysts modified by perfluorohexyl ponytail in the alkoxybenzylidene ligand

…, M Kvíčalová, J Cvačka, A Březinová

Index: Kvicala, Jaroslav; Schindler, Martin; Kelbichova, Vendula; Babunek, Mario; Rybackova, Marketa; Kvicalova, Magdalena; Cvacka, Josef; Brezinova, Anna Journal of Fluorine Chemistry, 2013 , vol. 153, p. 12 - 25

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Citation Number: 10

Abstract

Abstract The alkoxybenzylidene ligand of Hoveyda–Grubbs 1st and 2nd generation catalysts was modified with one or two perfluorohexyl groups by Ullmann reaction with the aim to improve both the fluorophilicity and activity of the catalyst. While bis ( ...