Homoleptic Tris-Diphosphine Re (I) and Re (II) Complexes and Re (II) Photophysics and Photochemistry

JJ Adams, N Arulsamy, BP Sullivan…

Index: Cloke, F. Geoffrey N.; Fyne, Peter J.; Gibson, Vernon C.; Green, Malcolm L. H.; Ledoux, Marc J.; et al. Journal of Organometallic Chemistry, 1984 , vol. 277, # 1 p. 61 - 74

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Citation Number: 3

Abstract

... 49) For the unsymmetrical complex fac-[(Me 2 PCH 2 PPh 2 ) 3 Re] + , 31 P NMR spectra showed two doublets centered at −45.9 and −63.3 ppm with 2 J PP (trans) = 94 Hz, which show unresolved 2 J PP (cis ... The more powerful oxidant (4-BrC 6 H 4 ) 3 N + B(C 6 F 5 ) 4 ...