Tetrahedron Letters

Specific deamination of 4-amino-1, 2, 4-triazin-5 (4H)-ones by catalytic oxidation with t-butylhydroperoxide. A chemical model for metabolism of 1, 2, 4-triazine …

Y Nakayama, Y Sanemitsu, H Yoshioka, A Nishinaga

Index: Nakayama, Y.; Sanemitsu, Y.; Yoshioka, H.; Nishinaga, A. Tetrahedron Letters, 1982 , vol. 23, # 24 p. 2499 - 2500

Full Text: HTML

Citation Number: 6

Abstract

Abstract The oxidation of 4-amino-1, 2, 4-triazine herbicides (1) with t-butylhydroperoxide catalyzed by Co (Salen) resulted in the specific deamination of the 4-amino group, providing a chemical model for the metabolism of the herbicides.

 Related Synthetic Route

~24%