Intramolecular amine-induced [1, 3]-sigmatropic rearrangement in the reactions of aminophosphinites or phosphites with elemental sulfur or selenium

P Chandrasekaran, JT Mague…

Index: Kimura, Tsutomu; Murai, Toshiaki; Miwa, Akihiro; Kurachi, Daisuke; Yoshikawa, Haruhisa; Kato, Shinzi Journal of Organic Chemistry, 2005 , vol. 70, # 14 p. 5611 - 5617

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Citation Number: 33

Abstract

... Select a Journal or Book ... 14 We have reported the synthesis and organometallic chemistry of cyclodiphosphazanes containing ether-, thioether-, and amine-functionalized hemilabile ponytails ... The 31 P NMR spectrum of 12 shows a singlet at 71.3 ppm with 1 J PSe = 953 Hz ...