Synthesis and reactivity of sulfonamides containing boronate esters

XF He, H Zhang, CM Vogels, A Decken…

Index: He, Xiao-Feng; Zhang, Haiwen; Vogels, Christopher M.; Decken, Andreas; Westcott, Stephen A. Heteroatom Chemistry, 2004 , vol. 15, # 5 p. 369 - 375

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Citation Number: 2

Abstract

Abstract Sulfonamides containing pinacol protected boronate ester groups have been prepared by the addition of H 2 NC 6 H 4 Bpin (pin= O 2 C 2 Me 4) to sulfonyl chlorides p- RC 6 H 4 SO 2 Cl (R= CH 3, NO 2). Hydrogenation of the nitro derivatives afford the corresponding sulfanilamides without compromising the aryl-Bpin bond. The sulfanilamides were further functionalized to afford novel platinum complexes containing ...