Inorganic chemistry

Nucleophilic Reactivity and Oxo/Sulfido Substitution Reactions of MVIO3 Groups (M= Mo, W)

DV Partyka, RJ Staples, RH Holm

Index: Baker, Murray V.; Brown, David H.; Skelton, Brian W.; White, Allan H. Journal of the Chemical Society - Dalton Transactions, 1999 , # 9 p. 1483 - 1490

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Citation Number: 28

Abstract

... Found: C, 30.25; H, 5.46; N, 6.43; W, 28.68. ... a suspension of 100 mg (0.229 mmol) of [(Bu t 3 tach)MoO 3 ] in 10 mL of acetonitrile was added 152 mg (0.376 mmol) of Lawesson's reagent ([p-MeOC 6 H 4 P(S)S] 2 ). The reaction mixture immediately formed a brown solution that ...