Design of a semirigid molecule as a selective fluorescent chemosensor for recognition of Cd (II)

XL Tang, XH Peng, W Dou, J Mao, JR Zheng…

Index: Tang, Xiao-Liang; Peng, Xiao-Hong; Dou, Wei; Mao, Jie; Zheng, Jiang-Rong; Qin, Wen-Wu; Liu, Wei-Sheng; Chang, Jin; Yao, Xiao-Jun Organic Letters, 2008 , vol. 10, # 17 p. 3653 - 3656

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Citation Number: 118

Abstract

A new 8-hydroxyquinoline-based chemosensor possessing a semirigid structure was designed, and its fluorescent sensing behavior toward metalions was investigated. A prominent fluorescence enhancement only for Cd2+ was found in aqueous methanol solution. The results clearly suggest that the specific semirigid structure could selectively accommodate Cd2+ according to ionic radius, which would effectively suppress the ...