… and P-donor ligands: X-ray structures of [Rh (1, 5-COD) Q s],[Rh (1, 5-COD)(phen)] Q s· 0.5 H 2 O (HQ s= 1-phenyl-3-methyl-4-(2-thenoyl)-pyrazol-5-one) and [Rh (1, 5 …

C Pettinari, F Marchetti, A Cingolani, G Bianchini…

Index: Pettinari, Claudio; Marchetti, Fabio; Cingolani, Augusto; Bianchini, Gianluca; Drozdov, Andrei; Vertlib, Vyacheslav; Troyanov, Sergei Journal of Organometallic Chemistry, 2002 , vol. 651, # 1-2 p. 5 - 14

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Citation Number: 34

Abstract

Complexes [Rh (1, 5-COD)(Q)] have been prepared by the reaction between [Rh (1, 5-COD) Cl] 2 (1, 5-COD= 1, 5-cyclooctadiene) and HQ (where HQ= 1-phenyl-3-methyl-4-R-pyrazol-5- one: R= 2-thenoyl (HQs), 2-furanoyl (HQo) or tert-butylacetyl (HQT).[Rh (1, 5-COD)(Q)] react with N2-donor ligands such as 1, 10-phenanthroline (phen) or 2, 2-bipyridyl (bipy) yielding ionic compounds [Rh (1, 5-COD)(N2-donor)] Q. The substitutional lability of 1, 5-COD in [ ...