Peroxytrifluoroacetic acid oxidation of sulfides to sulfoxides and sulfones

CG Venier, TG Squires, YY Chen…

Index: Venier, Clifford G.; Squires, Thomas G.; Chen, Yu-Ying; Hussmann, Gregory P.; Shei, Juliana C.; Smith, Barbara F. Journal of Organic Chemistry, 1982 , vol. 47, # 19 p. 3773 - 3774

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Citation Number: 87

Abstract

PS-100 spectrometer, and the samples contained Freon-11 and Me4Si as internal standards. (1) (l-Bromo-2LL-trifluoroethyl)sulfur Pentafluoride. In a typical reaction a 10-mL stainless-steel Hoke cylinder was charged with 10 mmol of SF6CH=CF2 and 11.5 mmol of Brz and then placed in a 110 OC oven for 24 h. The cylinder was cooled to room temperature and the volatile material condensed onto Hg contained in a 50-mL Pyrex reador to remove ...