Tetrahedron letters

Asymmetric synthesis of γ-alkayl-α-methylene-γ-butyrolactones via 1, 6-remote induction using 2-[(tributylstannyl) methyl] propenamides

K Tanaka, H Yoda, Y Isobe, A Kaji

Index: Tanaka, Kazuhiko; Yoda, Hidemi; Isobe, Yutaka; Kaji, Aritsune Tetrahedron Letters, 1985 , vol. 26, # 10 p. 1337 - 1340

Full Text: HTML

Citation Number: 23

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Reaction of chiral 2-[(tributylstannyl)methyl]propenamides with aldehydes proceeded with 1,6-asymmetric induction to give, after hydrolysis, α,-methylene-γ-butyrolactones in enantiomeric excesses as high as 80%. ... All new compounds gave satisfactory spectral and analytical ...