Palladium-catalyzed oxidative heterocyclodehydration-alkoxycarbonylation of 3-yne-1, 2-diols: a novel and expedient approach to furan-3-carboxylic esters

B Gabriele, L Veltri, R Mancuso, P Plastina, G Salerno…

Index: Gabriele, Bartolo; Plastina, Pierluigi; Salerno, Giuseppe; Mancuso, Raffaella; Costa, Mirco Organic Letters, 2007 , vol. 9, # 17 p. 3319 - 3322

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Citation Number: 21

Abstract

A novel and convenient approach to furan-3-carboxylic esters 2 is presented, based on palladium-catalyzed direct oxidative carbonylation of readily available 3-yne-1, 2-diols 1. The process, corresponding to a sequential combination between a 5-endo-dig ...