Reactions of Phenylenedioxytrihalophosphoranes with Arylacetylenes: IV. 1 Features of the Reaction of 2, 2, 2, 4, 5, 6, 7-Heptachlorobenzo [d]-1, 3, 2λ5- …

VF Mironov, AT Gubaidullin, AA Shtyrlina…

Index: Mironov; Gubaidullin; Shtyrlina; Litvinov; Petrov; Konovalov'; Dobrynin; Zyablikova; Musin; Morozov Russian Journal of General Chemistry, 2002 , vol. 72, # 11 p. 1764 - 1783

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Citation Number: 7

Abstract

Abstract As shown by NMR and IR spectroscopy and high-resolution mass spectrometry, the major products of the reaction of 2, 2, 2, 4, 5, 6, 7-heptachlorobenzo [d]-1, 3, 2λ 5- dioxaphosphole with phenylacetylene are a six-membered heterocyclic compound, 2-oxo-4- phenyl-2, 5, 6, 7, 8-pentachlorobenzo [e]-1, 2λ 5 (2 H)-oxaphosphorine, and the E and Z isomers of 2-(2, 3, 4, 4, 5-pentachlorocyclohexadienon-6-yl)-2-phenylvinylphosphonic ...