Ene Reactions of Arylmethylenedihydropyrazoles with 4-Phenyl-3H-1, 2, 4-triazole-3, 5 (4H)-dione

EI Klimova, GM Martinez, BT Klimova, ZC Damian…

Index: Klimova; Martinez; Damian; Ortega; Mendez; Gutierrez; Vazquez Synthesis, 2002 , # 13 p. 1891 - 1897

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Citation Number: 5

Abstract

Abstract: 2-Acetyl-3-aryl-7-arylmethylene-3, 4, 5, 6, 7, 9-hexahydro-2H-indazoles enter into the ene reaction with 4-phenyl-3H-1, 2, 4-triazole-3, 5 (4H)-dione to give the corresponding monoene adducts. Under analogous conditions, 3-aryl-7-arymethylene-2-methyl-3, 4, 5, 6, 7, 9-hexahydro-2H-indazoles give mono-and polyaddition products. The structures of compounds obtained were established using UV, IR, 1H and 13C NMR spectroscopy and ...