NMR study of the naphtho-1, 3-dithioles formed from carbamodithioates and 2, 3-dichloro-1, 4-naphthoquinone

…, KM El-Shaieb, AA Hassan, TMI Bedair

Index: Aly, Ashraf A.; Brown, Alan B.; El-Shaieb, Kamal M.; Hassan, Alaa A.; Bedair, Tarek M.L. Journal of Chemical Research, 2009 , # 11 p. 689 - 691

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Abstract

Reaction of triethylammonium 1, 2-ethanediylbis (carbamodithioate) with 2, 3-dichloro-1, 4- naphthoquinone in DMF furnished N, N'-ethylenebis (2-iminonaphtho [2, 3-d][1, 3] dithiole-4, 9-dione) in 94% yield. Triethylammonium N-arylcarbamodithioates reacted with 2, 3-dichloro- 1, 4-naphthoquinone to give 2-(N-arylimino) naphtho [2, 3-d][1, 3] dithiole-4, 9-diones in good yields. NMR spectroscopic data of the products are discussed.