The preparation of substituted thionocarbamates

AF McKay, DL Garmaise, GY Paris…

Index: McKay,A.F. et al. Canadian Journal of Chemistry, 1960 ,  vol. 38, p. 2042 - 2052            

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Citation Number: 15

Abstract

The thionocarbamate derivatives in Tables I-IV were prepared by one of the following three methods: -HC1 -HC1 ROH + CSC12 -- ROC(S)CI + R'NH2 - RINHC(S)OR, ... (C?Hs),Z\J ROH + R'NCS - R'NHC @)OR, ... NaH ROH + R'NCS - R1NHC(S)OR. ... Route 1 was used to prepare both the aryl aryltl~ionocarbai~lates and the aryl aralkyl- thionocarbamates. Procedure 2 gave good results with arall~yl isothiocyanates but triethylamine did not catalyze the addition of ...