Palladium-catalyzed carbonylative cross-coupling of organoboranes with aryl iodides or benzyl halides in the presence of bis (acetylacetonato) zinc (II)

Y Wakita, T Yasunaga, M Akita, M Kojima

Index: Wakita, Yoshiaki; Yasunaga, Tomoyuki; Akita, Masahiro; Kojima, Masaharu Journal of Organometallic Chemistry, 1986 , vol. 301, p. C17 - C20

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Citation Number: 45

Abstract

Abstract Carbonylative cross-coupling reactions of organoboranes with aryl iodides and benzyl halides successfully catalyzed by dichlorobis (triphenylphosphine) palladium (II) in the presence of bis (acetylacetonato) zinc (II) produce unsymmetrical ketones in reasonable yields.

~80%

~75%

~66%

~71%

~73%

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