Photoelectron spectra of furylsilanes and their carbon analogs

BG Zykov, NP Erchak, VI Khvostenko, E Lukevits…

Index: Zykov, B.G.; Erchak, N.P.; Khvostenko, V.I.; Lukevits, E.; Matorykina, V.F.; Asfandiarov, N.L. Journal of Organometallic Chemistry, 1983 , vol. 253, # 3 p. 301 - 312

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Citation Number: 13

Abstract

Abstract The first vertical π-ionization energies of substituted furans as determined by photoelectron spectroscopy are compared with the results of CNDO/2 calculations. The analysis of the photoelectron spectra and quantum chemical calculations for furylsilanes, difurylsilanes and some carbon analogs has shown the importance of the p π-d π interaction as well as of the conjugation and necessity of the inclusion of silicon d-atomic orbitals into ...