Tetrahedron letters

C 3 epimerization and selective C 2 C 3 bond fission of alkyl chrysanthemate

G Suzukamo, M Fukao, M Tamura

Index: Suzukamo, Gohfu; Fukao, Masami; Tamura, Mitsuhisa Tetrahedron Letters, 1984 , vol. 25, # 15 p. 1595 - 1598

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Citation Number: 17

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Treatment of alkyl chrysanthemate with Lewis acid leads to C 3 epimerization, while protonic acid treatment gives rise to selective C 2 C 3 bond cleavage. The latter method is successfully applied to the synthesis of optically active tetrahydrolavandulol. ... The isomer ratio was ...