Action of hydrazines, hydroxylamine, and urea on 2-aryl-4-(chloromethyl)-1, 3, 4-oxadiazoline-5-thiones

AA El-Barbary, I Islam…

Index: El-Barbary, Ahmed A.; Islam, Inas; Hashem, Abdel-Fattah M. Journal of Chemical & Engineering Data, 1984 , vol. 29, # 4 p. 477 - 479

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Abstract

Compounds IVa, e, h, i were cyclized with the elimination of hydrogen sulfide on heating in an oil bath at 5-10 OC over their melting points yielding 2, 3dihydro-6-phenyCs-triazoio [3, 4- b 1-[1, 3, 4] aadiazde (VI)(see Chart 11). Compounds VI reacted with methyl iodide, forming compounds VIIa-c. Compounds III reacted also with hydroxylamine hydrochloride, urea, and thiourea, yielding 2-aryi-4-(aminomethylF