Tetrahedron Letters

A novel anthraquinone annelation. A new approach to aklavinones.

Z Ahmed, MP Cava

Index: Ahmed, Zareen; Cava, Michael P. Tetrahedron Letters, 1981 , vol. 22, # 52 p. 5239 - 5242

Full Text: HTML

Citation Number: 7

Abstract

Abstract 1-Hydroxyanthraquinone has been annelated to a tetracyclic ketoester containing the major structural features of 4-deoxyaklavinone. The cyclization of the A-ring involves the first case of an anionic alkylation of an anthraquinone at a position which is not ortho to a phenolic function.