Syntheses and crystal structures of 1D tubular chains and 2D polycatenanes built from the asymmetric 1-(1-imidazolyl)-4-(imidazol-1-ylmethyl) benzene ligand with …

HF Zhu, W Zhao, T Okamura, J Fan, WY Sun…

Index: Zhu, Hui-Fang; Zhao, Wei; Okamura, Taka-Aki; Fan, Jian; Sun, Wei-Yin; Ueyama, Norikazu New Journal of Chemistry, 2004 , vol. 28, # 8 p. 1010 - 1018

Full Text: HTML

Citation Number: 63

Abstract

Reactions of a new asymmetric ligand, 1-(1-imidazolyl)-4-(imidazol-1-ylmethyl) benzene (IIMB), with various metal [Cd (II), Mn (II), Zn (II)] salts led to the formation of molecular, one- (1D) and two-dimensional (2D) architectures [Cd (IIMB) 2 (H2O)(SO4)]· 7.5 H2O 1,[Cd (IIMB) 2Cl2]· H2O 2,[Cd (IIMB) 4 (H2O) 2](NO3) 2· 5H2O 3,[Cd (IIMB)(OAc) 2]· H2O 4,[Mn (IIMB) 2 (SO4)(H2O)]· 8.2 H2O 5,[Mn (IIMB) 4 (H2O) 2] Cl2· 5H2O 6 and [Zn (IIMB) 2] 4 (NO3) 8· ...