Synthesis and characterization of" tailed picket fence" porphyrins

…, KM Doxsee, TR Halbert, E Bunnenberg…

Index: Collman, James P.; Brauman, John I.; Doxsee, Kenneth M.; Halbert, Thomas R.; Bunnenberg, Edward; et al. Journal of the American Chemical Society, 1980 , vol. 102, # 12 p. 4182 - 4192

Full Text: HTML

Citation Number: 189

Abstract

Abstract: The synthesis of “picket fence” porphyrin derivatives bearing covalently attached axial bases is described. These porphyrins have been well characterized, primarily as the iron (I1) complexes, meso-tri (a, a, ao-pivalamidophenyl)-Po-5-(N-imidazolyl) valeramidophenylporphyrinatoiron (II) and meso-tri (a, a, c~-o-pivalamidophenyl)-~-o-4-(N- imidazolyl) butyramido-phenylporphyrinatoiron (II), by UV/visible, MCD,'H NMR, and ...