The Journal of Organic Chemistry

Induced decomposition of tert-butyl peroxide by ether radicals. Nuclear magnetic resonance study

SH Goh

Index: Goh,S.H. Journal of Organic Chemistry, 1972 , vol. 37, p. 3098 - 3101

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Citation Number: 1

Abstract

An examination of the products of the decomposition of tsrt-butyl peroxide in 4-chlorobenzyl ethyl ether and 3, 4-dichlorobenzyl phenyl ether shows that the formed mixed acetals of the type ArCH (0R) Ot-Bu partially decomposed. The formation of the mixed acetal PhCB (0Me) Ot-Bu in the decomposition of tert-butyl peroxide in benzyl methyl ether was found to be promoted in the presence of added chlorinated solvents. o-Dichlorobenzene was found to ...

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