Inorganic Chemistry

Direct fluorination of hexamethyldigermane and hexamethyldisilane

RE Aikman, RJ Lagow

Index: Aikman, Robert E.; Lagow, Richard J. Inorganic Chemistry, 1982 , vol. 21, p. 524 - 526

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Citation Number: 5

Abstract

Controlled direct fluorination at low temperatures with careful manipulation of temperature and fluorine dilution is capable of preserving molecular structures that would normally be destroyed. As a result, a wide variety of organic, inorganic, and organometallic compounds have been synthesized.'" The preservation of germanium and silicon carbon bonds during fluorination'earlier suggested the possibility that this technique might be capable of ...