Novel phosphite palladium complexes and their application in C–P cross-coupling reactions

…, M Lutz, AL Spek, GPM van Klink, G van Koten…

Index: Li, Jie; Lutz, Martin; Spek, Anthony L.; Van Klink, Gerard P.M.; Van Koten, Gerard; Klein Gebbink, Robertus J.M. Journal of Organometallic Chemistry, 2010 , vol. 695, # 24 p. 2618 - 2628

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Citation Number: 3

Abstract

A mono-and a 1, 3-bis-phosphite arene ligand based on 2, 2′-biphenol have been synthesized in order to study the synthesis of the corresponding palladium (II) complexes starting from different Pd precursors. Novel bis-phosphite palladium complex 1 [PdCl2 (L) 2](L= dibenzo [d, f][1, 3, 2] dioxaphosphepin, 6-phenoxy), C, P-chelate bonded monophosphite palladium complex 2 [Pd (κ2-L)(μ-Cl)] 2, and PCP-pincer palladium ...