Functionally substituted amides and esters of 3, 4, 4-trichloro-3-butenoic acid

…, RV Kaberdin, KL Moiseichuk, AP Yuvchenko…

Index: Petkevich; Dikusar; Potkin; Kaberdin; Moiseichuk; Yuvchenko; Kurman Russian Journal of General Chemistry, 2004 , vol. 74, # 4 p. 586 - 593

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Citation Number: 8

Abstract

Abstract Substituted amides and esters of 3, 4, 4-trichloro-3-butenoic acid were prepared by reactions of its chloride with appropriate amines and alcohols. Treatment of 3, 4, 4-trichloro- 3-butenomorpholide and tert-butyl 3, 4, 4-trichloro-3-butenoate results in nucleophilic substitution of the internal chlorine atom with the morpholine residue, accompanied by prototropic allyl rearrangement.