Insect pheromones and their analogues. XXII. Methyl-branched pheromones based on 4-methyltetrahydropyran. Synthesis of racemic 2-acetoxy-3, 7- …

VN Odinokov, GY Ishmuratov, RY Kharisov…

Index: Odinokov, V. N.; Ishmuratov, G. Yu.; Kharisov, R. Ya.; Tolstikov, G. A. Chemistry of Natural Compounds, 1989 , vol. 25, # 4 p. 492 - 494

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Abstract

Abstract A synthesis is proposed of racemic 2-acetoxy-3, 7-dimethylpentadecane—the sex attractant (diprionyl acetate) of plane sawflies of the genera Diprion and Neodiprion on the basis of the regioselective transformation of bifunctional products of the cleavage of 4- methyltetrahydropyran.