An Inexpensive and Convenient Procedure for Chloromethylation of Aromatic Hydrocarbons by Phase Transfer Catalysis in Aqueous Media

…, Q Ge, P CHENG WANG, SBIN ZHANG…

Index: Hu, Yu Lin; Lu, Ming; Ge, Qiang; Wang, Peng Cheng; Zhang, Sheng Bin; Lu, Ting Ting Journal of the Chilean Chemical Society, 2010 , vol. 55, # 1 p. 97 - 102

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Citation Number: 2

Abstract

Chloromethylation of aromatic hydrocarbons was a very widely used reaction for well over half a century, both on a laboratory and industrial scale, and has been widely applied in synthesis of a variety of fine or special chemicals such as pharmaceuticals, agrochemicals, dyes, flavors and fragrances, monomers, additives, etc 1-21 . The reaction of aromatic hydrocarbons with hydrochloric acid and trioxane or paraformaldehyde as a formaldehyde precursor gave ...