Tetrahedron letters

IPy 2 BF 4 is also a useful reagent for stereospecific iodine-silicon exchange in open chain trimethylsilylalkenes

J Barluenga, LJ Alvarez-García, JM González

Index: Barluenga, Jose; Alvarez-Garcia, Lorenzo J.; Gonzalez, Jose M. Tetrahedron Letters, 1995 , vol. 36, # 12 p. 2153 - 2156

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Citation Number: 26

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Reaction of the title monosubstituted vinylsilanes with IPy 2 BF 4 /HBF 4 gives iodoalkenes through the ipso-substitution process with stereospecific retention of configuration. ... To account for the retention of configuration, TMS-group elimination is intended taking place by nucleophilic ...