High-pressure NMR study of transport and relaxation in complex liquid of 2-ethylhexyl cyclohexanecarboxylate and 2-ethylhexyl benzoate

…, ST Adamy, PJ Grandinetti, Y Masuda…

Index: Jonas, J.; Adamy, S. T.; Grandinetti, P. J.; Masuda, Y.; Morris, S. J.; et al. Journal of Physical Chemistry, 1990 , vol. 94, # 3 p. 1157 - 1164

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Citation Number: 29

Abstract

The self-diffusion coefficients, densities, and shear viscosities of liquid 2-ethylhexyl cyclohexanecarboxylate (EHC) were measured as a function of pressure from 1 to 4500 bar within the temperature range from-20 to 80'C. The Stokes-Einstein equation is applicable over 5 order of magnitude changes in self-diffusion and viscosity. The experimental data obtained are compared to those for the complex liquid of 2-ethylhexyl benzoate (EHB) in ...