A new cycloheptenone annulation method: use of the bifunctional reagent (Z)-5-iodo-1-tributylstannylpent-1-ene in organic synthesis

E Piers, SD Walker, R Armbrust

Index: Piers, Edward; Walker, Shawn D.; Armbrust, Ralph Journal of the Chemical Society, Perkin Transactions 1, 2000 , # 5 p. 635 - 637

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Citation Number: 2

Abstract

A new seven-membered annulation method that employs (Z [hair space])-5-iodo-1- tributylstannylpent-1-ene (1) as a key reagent and that is exemplified by the conversion of compounds 6, 12, 13, 20, 25, and 26 into the annulation products 11, 18, 19, 24, 33, and 34, respectively, is reported.