Reactivity of Germene Mes2Ge CR2 with Cumulative Unsaturation-Containing Compounds: Synthesis of New Germanium Heterocycles

S Ech-Cherif El Kettani, M Lazraq…

Index: Ech-Cherif El Kettani, Sakina; Lazraq, Mohamed; Ranaivonjatovo, Henri; Escudie, Jean; Couret, Claude; Gornitzka, Heinz; Atmani, Aziz Organometallics, 2005 , vol. 24, # 22 p. 5364 - 5368

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Citation Number: 13

Abstract

Germene 1 reacts with the CO and CS double bonds respectively of phenylisocyanate and methylisothiocyanate by [2+ 2] cycloadditions, leading to four-membered ring derivatives. With CS2, a dithiagermolane and a dithiadigermetane are obtained; the first step of this ...