The chemistry of organometallic compounds containing a tin zinc bond. The occurrence of 1, 2-intermetallic migrations of organic groups

FJA Des Tombe, GJM Van Der Kerk…

Index: Tombe, F. J. A. des; Kerk, G. J. M. van der; Noltes, J. G. Journal of Organometallic Chemistry, 1972 , vol. 43, p. 323 - 331 Full Text View citing articles Show Details Tombe, F. J. A. des; Kerk, G. J. M. van der; Creemers, H. J. M. C.; Carey, N. A. D.; Noltes, J. G. Journal of Organometallic Chemistry, 1972 , vol. 44, p. 247 - 252 Full Text View citing articles Show Details Tombe, F. J. A. des; Kerk, G. J. M. van der; Creemers, H. J. M. C.; Noltes, J. G. Chemical Communications (London), 1966 , p. 914 - 915 Full Text Show Details Gmelin Handbook: Sn: Org.Verb.4, 1.2.1.1.7.4.7, page 84 - 86

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Citation Number: 19

Abstract

Abstract Triphenyltin-zinc compounds are easily accessible by means of hydrostannolysis reactions of zinc carbon bonds in coordinatively saturated organozinc compounds. The chemical behaviour of (triphenyltin) zinc chloride was found to depend greatly on the coordination state of the zinc atom. In the absence of strongly coordinating ligands, 1, 2- intermetallic migration of a phenyl group from tin to zinc occurs. In consequence it ...