Electron-transfer-induced tautomerization in methylindanones: Electronic control of the tunneling rate for enolization

…, T Bally, T Filipiak, A Marcinek, J Gebicki

Index: Bally, Thomas; Bernhard, Stefan; Matzinger, Stephan; Roulin, Jean-Luc; Narahari Sastry; Truttmann, Leo; Zhu, Zhendong; Marcinek, Andrzej; Adamus, Jan; Kaminski, Rafal; Gebicki, Jerzy; Williams, Ffrancon; Chen, Guo-Fei; Fuelscher, Markus P. Chemistry - A European Journal, 2000 , vol. 6, # 5 p. 858 - 868

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Citation Number: 10

Abstract

The radical cations generated from 4-methyl-and 4, 7-dimethylindanone, as well as their deuterated isotopomers, isolated in Argon matrices, were found to undergo enolization to the corresponding enol radical cations at rates that differ by orders of magnitude. It is shown

The rearrangement of the cubane radical cation in solution

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Catalysis of symmetry-restricted reactions by transition met...

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Photochemical precursor to cyclobutadiene

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3, 4-Diazabenzvalene, the azoalkane precursor to tetrahedran...

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