A Convenient Synthesis of 4-(2, 2-Dichloroethenyl)-5, 5-dimethyltetrahydro-2-furanone Derivatives, a Key Intermediate of Permethrinic Acid

S Tsuboi, E Amano, A Takeda

Index: Tsuboi; Amano; Takeda Bulletin of the Chemical Society of Japan, 1984 , vol. 57, # 3 p. 802 - 805

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Citation Number: 2

Abstract

A key intermediate of 2-(2, 2-dichloroethenyl)-3, 3-dimethylcyclopropanecarboxylic acid, 3- alkoxycarbonyl (or acyl)-4-(2, 2-dichloroethenyl)-5, 5-dimethyltetrahydro-2-furanone was prepared by the base-catalyzed condensation of 2-methyl-3, 5, 5-trichloro-4-penten-2-ol with acetate derivatives such as malonic esters, acetoacetic esters, and benzoylacetate. The reactivity of 3-acetyl-4-(2, 2-dichloroethenyl)-5, 5-dimethyltetrahydro-2-furanone to an ...