The LBAs (Lewis acid-assisted Brønsted acid catalysis) is proposed as possible mechanistic process in the simple FeCl3-catalyzed Michael reactions of chalcones with active methylene compounds in organic solvents. And iron salts were found to be effective promoters in the asymmetric Michael addition of 4-hydroxycoumarin to α, β-unsaturated ketone, which resulted in excellent yield and high level of enantioselectivity (up to 91% ee) in the ...