Catalytic ethylene polymerisation in carbon dioxide as a reaction medium with soluble nickel (II) catalysts

…, G Franciò, W Leitner, S Mecking

Index: Bastero, Amaia; Francio, Giancarlo; Leitner, Walter; Mecking, Stefan Chemistry - A European Journal, 2006 , vol. 12, # 23 p. 6110 - 6116

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Citation Number: 24

Abstract

Abstract A series of neutral Ni II–salicylaldiminato complexes substituted with perfluorooctyl- and trifluoromethyl groups,[Ni {κ 2-N, O-6-C (H)[DOUBLE BOND] NAr-2, 4-R′ 2 C 6 H 2 O}(Me)(pyridine)](6 a: Ar= 2, 6-{4-(F 17 C 8) C 6 H 4} 2 C 6 H 3, R′= I; 6 b: Ar= 2, 6-{4-(F 3 C) C 6 H 4} 2 C 6 H 3, R′= I; 6 c: Ar= 2, 6-{3, 5-(F 3 C) 2 C 6 H 3} 2 C 6 H 3, R′= 3, 5-(F 3 C) 2 C 6 H 3; 6 d: Ar= 2, 6-{4-(F 17 C 8) C 6 H 4} 2 C 6 H 3, R′= 3, 5-(F 3 C) 2 C 6 H 3; 6 e ...