The collisionally induced dissociation of allyl and 2??propenyl cations

…, JL Holmes, AA Mommers, JE Szulejko

Index: Burgers, Peter C.; Holmes, John L.; Mommers, Alexander A.; Szulejko, Jan E. Organic Mass Spectrometry, 1983 , vol. 18, # 12 p. 596 - 600

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Citation Number: 14

Abstract

Abstract Pure [CH 2 CHCH 2]+ and equation image ions are generated only in metastable fragmentations of [CH 2 [DOUBLE BOND] CHCH 2 X]+, X= Cl, Br, I, and [CH 3 CX [DOUBLE BOND] CH 2]+, X= Br, I, respectively. For ion source generated [C 3 H 5]+ ions there is some structural interconversion. The structure characteristic feature of their collisional activation mass spectra is the ratio m/z 27 ([C 2 H 3]+): m/z 26 ([C 2 H 2]+). For equation image the ...