Journal of organometallic chemistry

Funktionelle Phosphane: Part XI. Optisch reine β-Aminophosphane und β-Aminophosphinite für die komplexkatalysierte Reduktion organischer …

L Dahlenburg, R Götz

Index: Dahlenburg, Lutz; Goetz, Rainer Journal of Organometallic Chemistry, 2001 , vol. 619, # 1-2 p. 88 - 98

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Citation Number: 75

Abstract

The preparation of optically active β-aminophosphane ligands,(−)-(1R, 2S)-Ph2PCH (Ph) CH (Me) NH2 (5),(+)-(1S, 2S)-Ph2PCH (Ph) CH (Me) NH2 (6),(−)-(1R, 2R)-Ph2PCH (Ph) CH (Me) NHMe (7), and (1R, 2S)-Ph2PCH (Ph) CH (Me) NHSO2Me (8), as well as of related β- aminophosphinites,(+)-(1R, 2S)-Ph2POCH (Ph) CH (Me) NH2 (9),(−)-(1R, 2R)-Ph2POCH (Ph) CH (Me) NHMe (10),(+)-(1S, 2S)-Ph2POCH (Ph) CH (Me) NHMe (11), and (−)-(1R, ...