Structural and conformational analysis of 1??oxaspiro [2.5] octane and 1??oxa??2??azaspiro [2.5] octane derivatives by 1H, 13C, and 15N NMR

R Montalvo??González…

Index: Montalvo-Gonzalez, Ruben; Ariza-Castolo, Armando Magnetic Resonance in Chemistry, 2012 , vol. 50, # 1 p. 33 - 39

Full Text: HTML

Citation Number: 0

Abstract

Three-membered heterocyclic rings, which can be converted into a large number of functional groups,[1] have been invaluable intermediates in organic synthesis. They are easily synthesized from the oxidation of alkenes (oxiranes)[2] or imines (oxaziridines)[3] with preservation of their configuration, and their rings are easily broken through addition reactions. Nitrogen centers functionalized with three different substituents are usually ...