Synthesis and X-ray crystal structures of dimorpholino-di-,-tri-, and-tetra-selane, and dipiperidinotetraselane

O Foss, V Janickis

Index: Foss,O.; Janickis,V. Journal of the Chemical Society, Chemical Communications, 1977 , p. 833 - 834

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Abstract

Summary The title compounds have been prepared by heating black selenium powder with the amine in the presence of red lead ; their X-ray crystal structures have been determined. ... WHEREAS di- and poly-sulphur diamides are well kn ~ wn , l - ~ the only example of a selenium analogue appears to be a brick-red solid of mp 90-95 "C described as being essen- tially dimorpholinotriselane.6 Levi2 in 193 1 prepared dipiperidino-tri- and -tetra- sulphane ...