Journal of Molecular Spectroscopy

Resonance-enhanced multiphoton ionization detection of a new 3Σ+-a3Π band system in CS

Y Ono, JL Hardwick

Index: Ono, Y.; Hardwick, J. L. Journal of Molecular Spectroscopy, 1986 , vol. 119, p. 107 - 119

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Citation Number: 8

Abstract

Abstract Resonance-enhanced multiphoton ionization has been used to detect absorption transitions from the nascent states of CS produced in the two-photon laser flash photolysis of CS 2. Transitions are seen from the a 3 Π state of CS to a previously unobserved 3 Σ+ state. Rotational assignments of the (1, 0),(0, 0),(0, 1), and (0, 2) bands have been made; the derived constants for those bands are similar to those of the CS+ ion, in good agreement ...