Journal of organometallic chemistry

Photochemically reactive polymers; the synthesis and photochemistry of amide polymers and model compounds containing metal–metal bonds and internal radical …

GF Nieckarz, JJ Litty, DR Tyler

Index: Nieckarz, Gregory F.; Litty, John J.; Tyler, David R. Journal of Organometallic Chemistry, 1998 , vol. 554, # 1 p. 19 - 28

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Citation Number: 24

Abstract

The synthesis and photochemistry of a photochemically reactive polymer that has internal metal-radical traps (chlorine atoms) along its backbone is reported. Reaction of the organometallicdiamine'(CpCH2CH2NH2) 2Mo2 (CO) 6 with an activated mixed anhydride derivative of 3, 4-dichlorohexanedioic acid gave the polymer [–CHClCH2C (O) NHCH2CH2 (η5-C5H4)(CO) 3Mo–Mo (CO) 3 (η5-C5H4) CH2CH2NHCOCH2CHCl–] n. The ...