Heteroatom Chemistry

Design, synthesis, and evaluation of unsymmetrical difluoro??boron complexes with imidazoline as potential fungicides

K Wang, J Cui, L Xie, X Qian

Index: Wang, Kewei; Cui, Jingnan; Xie, Lijuan; Qian, Xuhong Heteroatom Chemistry, 2009 , vol. 20, # 7 p. 418 - 424

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Citation Number: 2

Abstract

Abstract A series of unsymmetrical difluoro-boron (BF 2) complexes with pyridine and imidazoline were synthesized by reaction of new chelating ligands (arylmethyl- imidazolidinylidene)-pyridin-2-yl-amine with boron trifluoride diethyl etherate. All the ligands and BF 2 complexes were structurally characterized by IR, HRMS, 1 H, 13 C, 11 B, and 19 F NMR, indicating the bidentate complexation of imidazoline nitrogen and the pyridine ...