Liquid-phase synthesis of cyclic diene diepoxides using metal halides and hydrogen peroxide

KM Alimardanov, OA Sadygov, NI Garibov…

Index: Alimardanov, Kh. M.; Sadygov; Garibov; Abdullaeva, M. Ya. Russian Journal of Organic Chemistry, 2012 , vol. 48, # 10 p. 1302 - 1308 Zhurnal Organicheskoi Khimii, 2012 , vol. 48, # 10 p. 1307 - 1312,6

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Abstract

Abstract Optimal conditions were found for induced hydroxyhalogenation of cyclic dienes (tetrahydroindene, 4-vinylcyclohexene and 5-vinyl-and 5-cyclohexenylbicyclo [2.2. 1] hept-2- enes) in the system [MHlg-HA or HHlg]-H 2 O 2 (or NaClO). Dehydrohalogenation of the chloro-and bromohydrins thus obtained with powdered potassium carbonate gave the corresponding diepoxy derivatives, and their hydrolysis led to mixtures of stereoisomeric ...