The Journal of Physical Chemistry C

Determination and Comparison of Thermodynamic Driving Forces of Elementary Steps for the Reductions of Alkynes and the Corresponding Alkenes in Acetonitrile

SM Si, YH Fu, XQ Zhu

Index: Zhu, Xiao-Qing; Li, Xiu-Tao; Han, Su-Hui; Mei, Lian-Rui Journal of Organic Chemistry, 2012 , vol. 77, # 10 p. 4774 - 4783

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Abstract

In this work, five substituted 1-phenyl-2-benzensulfonyl ethynes and the corresponding five substituted 1-phenyl-2-benzensulfonyl ethenes were designed and synthesized as representatives of the polar alkynes and the polar alkenes. Thermodynamic driving forces of