Synthesis of bridgehead chloro-, bromo-and iodobicyclo [2.2. 2] octanes

J Kopecký, J Šmejkal

Index: Kopecky, Jan; Smejkal, Jaroslav Collection of Czechoslovak Chemical Communications, 1980 , vol. 45, # 11 p. 2965 - 2970

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Citation Number: 6

Abstract

Due to relative availability of bridgehead hydroxybicycIo[2.2.2]octanes or their acetates or methyl ethers1 - 5 these compounds became potential starting materials for preparation of other bridgehead derivatives of bicycIo[2.2.2]octanes. The pre- sent communication deals with preparation of bridgehead halogenobicycIo[2.2.2} octanes (except for the fiuoro derivatives6,7) from mentioned compounds. At the same time we were interested in partial transformation of hydroxy ...