Tetrahedron letters

Chelation controlled regioselective alkylation and 1, 4 chirality transfer in optically active 1-alkoxy-1, 4-cyclohexadienes

D Stanssens, D De Keukeleire, M Vandewalle

Index: Stanssens, Dirk; Keukeleire, Denis De; Vandewalle, Maurits Tetrahedron Letters, 1987 , vol. 28, # 36 p. 4195 - 4198

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Citation Number: 3

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Chelation controlled alkylation of optically active 1-alkoxy-1,4-cyclohexadienes leads to a mixture of 1,4-cyclohexadienes and 1,3-cyclohexadienes . The regio- and diastereoselectivities depend upon the nature of the chiral auxiliary and the reaction conditions.